Calcium Fluoride (CaF2)
single crystal is an optical material with high transmittance
in ultraviolet, visible and infrared regions of the spectrum:
0.15 ¦Ìm ~ 9 ¦Ìm range. Calcium Fluoride is widespread used
for optical windows, lenses and prisms in the IR application;
especially pure grades find useful application in the UV
and as UV Eximer (High power applications) laser windows.
Useful: This material has found wide use in high power laser
optics due to its low absorption; polished surfaces are
stable and will last several years under normal conditions;
due to its low refractive index, Calcium Fluoride can be
used without anti-reflection coating.
Main Properties
| Crystal
properties |
| Crystal
Growth Method |
Vacuum
Stockbarger |
| Max.
Size (mm) |
<250 |
| Optical
properties |
| Transmission
range (um) |
0.15~9 |
| Reflection
Loss, % for two surfaces at 5 ¦Ìm |
5.4 |
| Absorbance |
1.7¡Á10-4£¨3.8¦Ìm£© |
|
Refractive
Index |
See
below |
| Wavelength
(um) |
Refractive
Index (n) |
Wavelength
(um) |
Refractive
Index (n) |
| 0.1495 |
1.5800 |
4.0000 |
1.4069 |
| 0.1612 |
1.5490 |
5.0000 |
1.3990 |
| 0.2000 |
1.4951 |
6.0000 |
1.3856 |
| 0.3000 |
1.4540 |
7.0000 |
1.3693 |
| 0.4000 |
1.4419 |
8.0000 |
1.3498 |
| 0.5000 |
1.4365 |
9.0000 |
1.3268 |
| 1.0000 |
1.4289 |
10.0000 |
1.3002 |
| 2.0000 |
1.4239 |
11.0000 |
1.2676 |
| 3.0000 |
1.4179 |
12.0000 |
1.2299 |
| Transmission
Curve
|
See
below |
| |
| Crystallographic
properties |
| Syngony |
Cubic |
| Lattice Constant,
Å |
5.462 |
| Cleavability |
<111> |
| Molecular Weight |
78.08 |
| Physical
properties |
| Density,
at 291 K |
3.18g/cm3 |
| Hardness,
Mohs |
4
|
| Dielectric
Constant for 105 Hz |
6.76 |
| Melting
point, °C |
1360 |
| Thermal
Conductivity, W/m¡¤K at 36°C |
9.71 |
| Thermal
Expansion, 1/K |
(16.2
~ 19.4) ¡Á 10-6 |
| Specific
Heat Capacity, J/(kg¡¤°C) at 40°C |
887.6 |
| Knoop Hardness,
kg/mm2 |
178
[100], 160 [110] |
Young's Modulus,
Gpa
<100>
<111> |
146.1
89.9 |
Shear Modulus,
Gpa
<100>
<111> |
47.6
33.8 |
| Bulk
Modulus, GPa
|
82.7 |
| Debye
Temperature, K
|
510 |
| Elastic
Coefficients
|
C11=164,
C44=33.7, C12=53 |
| Poisson
Ratio
|
0.26 |
|
|