Fused Silica is the
glassy form of quartz and is thus isotropic. It is tough
and hard and has a very low expansion. Normal varieties
contain water that gives strong absorption in the IR. Water-free
varieties are available.
Vitreous silica is the generic term used to describe all
types of silica glass, with producers referring to the material
as either Fused Quartz or as Fused Silica. Originally, those
terms were used to distinguish between transparent and opaque
grades of the material. Fused Quartz products were those
produced from quartz crystal into transparent ware, and
Fused Silica described products manufactured from send into
opaque ware.
Today, however, advances in raw material beneficiation permit
transparent fusions from sand as well as from crystal. Consequently,
if naturally occurring crystalline silica (sand or rock)
is melted, the material is simply called Fused Quartz. If
the silicon dioxide is synthetically derived, however, the
material is referred to as synthetic Fused Silica.
These materials are ultra pure, single component glasses
(SiO2) with a unique combination of thermal, optical and
mechanical properties, which make them the preferred materials
for use in a variety of processes and applications where
other materials are not suitable. The very high purity (over
99.9%) ensures minimum contamination in process applications.
These materials can routinely withstand temperatures of
over 1250<C, and due to their very low coefficient of thermal
expansion can be rapidly heated and cooled with virtually
no risk of breakage due to thermal shock.
These materials are inert to most substances, including
virtually all acids, allowing their use in arduous and hostile
environments.
The dielectric properties and very high electrical receptivity
of these materials over a wide range of temperatures, together
with their low thermal conductivity allow their use as an
electrical and thermal insulating material in a range of
environments.
Fused Quartz is less expensive vitreous
silica formed by fusing naturally occurring quartz crystal
or lower grade synthetic stock material, The UV use is limited
to 250nm and this material is usually used for windows covering
visible wavelengths.
Fused Silica is vitreous silica formed
by fusing high purity synthetic material. The UV use can
be reached about 160nm.
Ultraviolet Grade
Fused Silica: JGS1 (China), equivalent to Suprasil
1 and 2 (Heraeus), Spectrosil A and B (Saint-Gobain) and
Corning 7940 (Corning), Dynasil 1100 and 4100 (Dynasil).
Optical Grade Fused Quartz: JGS2 (China),
equivalent to Homosil 1, 2 & 3 (Heraeus), Dynasil 1000
& 4000 and 5000 & 6000 (Dynasil)
IR grade Fused Silica: JGS3 (China), equivalent
to Suprasil 300 (Heraeus).
UV grade Fused Silica (JGS1) is synthetic amorphous
silicon dioxide of extremely high purity. This non-crystalline,
colorless silica glass combines a very low thermal expansion
coefficient with good optical qualities, and excellent transmittance
in the ultraviolet. Transmission and homogeneity exceed
those of crystalline quartz without the problems of orientation
and temperature instability inherent in the crystalline
form. Fused silica is used for both transmissive and reflective
optics, especially where high laser damage threshold is
required.
JGS1 is transparent in the ultraviolet and visible regions,
and has no absorption bands in the 170-250 nm wavelength
intervals. It has an intensive OH absorption band in the
interval of wavelength 2600-2800 nm.
JGS1 is used for optics operating in the deep UV and the
visible wavelength range (Laser Lenses, Windows, Prisms,
Mirrors, etc.). It is practically free of bubbles and inclusions.
Optical Grade Fused Quartz (JGS2) provides
good UV and visible transmission. It has almost the same
physical and chemical properties with JGS1. However only
in thin & small sheet pieces, JGS2 is virtually bubble-free.
Elements built from larger pieces will most likely contain
bubbles, so application should not be sensitive to these
inclusions. But in cases where simple light gathering and
strong mechanical properties are the primary goals, JGS2
grade provides excellent performance at a low price.
Ideal Applications for
JGS2:
Condenser optics not concerned with scatter or distortion
High temperature and pressure applications
Optical flats, microscope slides and sight glasses
IR grade Fused Silica (JGS3) is super purity synthetic fused
silica manufactured by melting of super pure ash in vacuum.
It is transparent in the ultraviolet, visible and infrared
spectral regions. It has no absorption bands in the visible
region and has no OH absorption band at 2700 nm ("water
band").
JGS3 combines excellent physical properties with outstanding
optical characteristics in the deep UV and the IR wavelength
range. It is the preferred material for transmission optics;
it is usually used in IR applications and also in those
requiring very wide wavelength range from DUV to MIR. However
the most common Fused Silica for infrared use is quite a
bit more expensive than Silicon and slightly less expensive
than Calcium Fluoride or ZnS Multi-spectral grade. Also
a commercial quality of IR quartz often contains many small
bubbles and should only be used for non-imaging applications.
RISING-EO can handle with JGS1 well into
10-5 S/D and lambda/20 grade.
Main Properties
| Difference properties |
| Parameter|Value |
JGS1 |
JGS2 |
JGS3 |
Maximum Size |
<Φ200mm |
<Φ300mm |
<Φ200mm |
Transmission Range
(Medium transmission ratio) |
0.17~2.10um
(Tavg>90%) |
0.26~2.10um
(Tavg>85%) |
0.25~3.50um
(Tavg>85%) |
OH- Content |
1200 ppm |
150 ppm |
5 ppm |
Fluorescence (ex 254nm) |
Virtually Free |
Strong v-b |
Strong V-B |
Impurity Content |
5 ppm |
20-40 ppm |
40-50 ppm |
Birefringence Constant |
2-4 nm/cm |
4-6 nm/cm |
4-10 nm/cm |
Melting Method |
Synthetic CVD |
Oxy-hydrogen melting |
Electrical melting |
| Applications |
Laser substrate: Window, lens, prism, mirror... |
Semiconductor and high temperature window |
IR substrate |
| Same properties |
| Density |
2.20g/cm3 |
| Abbe Constant |
67.6 |
| Refractive Index (nd) at 588nm
|
1.4586 |
| |
Refractive Index (n) |
Wavelength (um) |
Refractive Index (n) |
0.200 |
1.55051 |
1.000 |
1.45042 |
0.220 |
1.52845 |
1.064 |
1.44962 |
0.250 |
1.50745 |
1.100 |
1.44920 |
0.300 |
1.48779 |
1.200 |
1.44805 |
0.320 |
1.48274 |
1.300 |
1.44692 |
0.360 |
1.47529 |
1.500 |
1.4462 |
0.400 |
1.47012 |
1.600 |
1.44342 |
0.450 |
1.46557 |
1.700 |
1.44217 |
0.488 |
1.46302 |
1.800 |
1.44087 |
0.500 |
1.46233 |
1.900 |
1.43951 |
0.550 |
1.46008 |
2.000 |
1.43809 |
0.588 |
1.45860 |
2.200 |
1.43501 |
0.600 |
1.45804 |
2.400 |
1.43163 |
0.633 |
1.45702 |
2.600 |
1.42789 |
0.650 |
1.45653 |
2.800 |
1.42377 |
0.700 |
1.45529 |
3.000 |
1.41925 |
0.750 |
1.45424 |
3.200 |
1.41427 |
0.800 |
1.45332 |
3.370 |
1.40990 |
0.850 |
1.45250 |
3.507 |
1.40566 |
0.900 |
1.45175 |
3.707 |
1.39936 |
| Transmission Curve |
See below |
|
|
|
| Hardness |
5.5 - 6.5 Mohs' Scale 570 KHN 100 |
| Design Tensile Strength |
4.8x107 Pa (N/mm2) (7000 psi) |
| Design Compressive Strength |
Greater than 1.1x109 Pa (160,000 psi) |
| Bulk Modulus |
3.7x1010 Pa (5.3x106 psi) |
| Rigidity Modulus |
3.1x1010 Pa (4.5x106 psi) |
| Young's Modulus |
7.2x10-10 Pa (10.5x106 psi) |
| Poisson's Ratio |
0.17 |
| Coefficient of Thermal Expansion |
5.5x10-7cm/cm.<C (20<C-320<C) |
| Thermal Conductivity |
1.4 W/m.<C |
| Specific Heat |
670 J/kg.<C |
| Softening Point |
1683<C |
| Annealing Point |
1215<C |
| Strain Point |
1120<C |
| Electrical Receptivity |
7x107 ohm.cm (350<C) |
Dielectric Properties (20<C and 1 MHz)
Constant
Strength
Loss Factor
Dissipation Factor |
3.75
5x107 V/m
Less than 4x10-4
Less than 1x10-4 |
| Velocity of Sound-Shear Wave |
3.75x103 m/s |
| Velocity of Sound/Compression Wave |
5.90x103 m/s |
| Sonic Attenuation |
Less than 11 db/m MHz |
Permeability Constants (cm3mm/cm2 sec cm of
Hg)
Helium
Hydrogen
Deuterium
Neon |
(700<C)
210x10-10
21x10-10
17x10-10
9.5x10-17 |
| Chemical Stability (except hydrofluoric) |
High resistance to water and acids |
|
|