Germanium (Ge) is the
preferred lens and window material for high performance
infrared imaging systems in the 8¨C12 ¦Ìm wavelength band.
Its high refractive index makes Ge ideal for low power imaging
systems because of minimum surface curvature. Chromatic
aberration is small, often eliminating the need for correction.
Germanium is most widely used for lenses and windows in
IR systems operating in the 2 ¦Ìm - 12 ¦Ìm range. Its transmission
is very temperature sensitive, becoming opaque near 100¡ãC.
Environment does not cause problems because Germanium is
inert, mechanically rugged, and fairly hard.
Germanium is a high index material that is used to manufacture
Attenuated Total reflection (ATR) prisms for spectroscopy.
Its refractive index is such that germanium makes an effective
natural 50% beamsplitter without the need for coatings.
It is also used extensively as a substrate for production
of optical filters. Germanium covers the whole of the 8-14
micron thermal band and is used in lens systems for thermal
imaging. It can be AR coated with diamond producing an extremely
tough front optic.
Application as window, lens, beamsplitter, ATR prism or
filter in spectrometers and in thermal imaging.
Main Properties
| Crystal
properties |
| Crystal
Growth Method |
Czochralski pulling
techniques |
| Maximum
Size |
<¦µ250mm |
| Optical
properties |
| Transmission
Range |
2.0~17um |
| Reflection
Loss, for two surfaces at 11µm
| 53%
|
| Refractive
Index |
See below |
| Wavelength
(um) |
Refractive
Index (n) |
Wavelength
(um) |
Refractive
Index (n) |
| 2.0 |
4.1079 |
9.0 |
4.0047 |
| 3.0 |
4.0446 |
10.0 |
4.0040 |
| 4.0 |
4.0242 |
11.0 |
4.0031 |
| 5.0 |
4.0153 |
12.0 |
4.0029 |
| 6.0 |
4.0106 |
12.5 |
4.0024 |
| 7.0 |
4.0076 |
13.02 |
4.0021 |
| 8.0 |
4.0053 |
15.0 |
4.0017 |
| Transmission
Curve |
See
below |
|
|
|
|
|
|
| Crystallographic
properties |
| Syngony |
Cubic |
| Crystal Form |
Poly or Single Crystal |
| Lattice Constant,
Å |
5.66 |
| Cleavability |
<111>, non-perfect |
| Molecular Weight |
72.60 |
| Physical
properties |
| Density, at 20 °C |
5.33 |
| Hardness,
Mohs |
6.3 |
| Dielectric
Constant for 9.37 ¡Á 109 Hz at 300 K |
16.6 |
| Melting
|
937 |
| Thermal
Conductivity, W/m¡¤K at at 293 K |
59 |
| Thermal
Expansion, 1/K at 298 K |
6.1 ¡Á 10-6 |
| Specific
Heat Capacity, J/(kgK) at 273-373 K |
0.074 |
| Bandgap,
eV |
0.67 |
| Knoop
Hardness, kg/mm2 |
800 |
| Young's
Modulus, Gpa |
102.66 |
| Shear
Modulus, GPa |
67.04 |
| Bulk
Modulus, GPa |
77.86 |
| Debye
Temperature, K |
370 |
| Poisson's
Ratio |
0.278 |
| Elastic
Coefficient |
C11=129, C12=48.3,
C44=67.1 |
| Apparent
Elastic Limit |
89.6 MPa (13000psi) |
| Chemical
properties |
| Solubility
in water |
None |
| Solubility
in acids |
Soluble |
| Molecular
Weight |
72.59 |
|
|