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Magnesium Fluoride (MgF2) transmits well into the VUV region at the hydrogen Lyman-alpha line (121nm) and beyond. Application as window, lens, in most VUV region optics and is excellent for excimer laser use.

MgF2 is a positive birefringent crystal with high optical transmittance from the vacuum ultraviolet to the infrared spectrum region. It is resistant to mechanical and thermal shock, to radiation, and is chemically stable.

Main Properties

Crystal properties

Crystal Growth Method Vacuum Stockbarger
Max. Size (mm) <100
Optical properties
Transmission range (um) 0.12~7.00
Reflection Loss, % for two surfaces at 5 μm 4.8
Refractive Index See below
Wavelength (um)
No
Ne
Wavelength (um)
No
Ne
0.121
1.62750
1.63200
0.656
1.37661
1.38835
0.140
1.50950
1.52300
1.000
1.37360
1.38521
0.178
1.43975
1.45365
2.000
1.36800
1.37922
0.200
1.42309
1.43657
3.000
1.36000
1.37060
0.300
1.39298
1.40543
4.000
1.35250
1.36220
0.436
1.38203
1.39402
5.000
1.33020
1.33930
0.488
1.38016
1.39206
6.000
1.32420
1.33150
0.588
1.37770
1.38960
7.000
1.30440
1.31010
Transmission Curve See below

Crystallographic properties

Syngony Tetragonal
Lattice Constant, Å a=4.64; c=3.06
Cleavability (100),(110), imperfect
Physical properties
Density, at 291 K 3.18g/cm3 
Hardness, Mohs 6
Dielectric Constant for 95x103 - 42x106 Hz 5.45
Melting point, °C 1255
Thermal Conductivity, W/m,K 3.14
Thermal Expansion, K
Parallel to c-axis (//)
Perpendicular to c-axis (— )

14 〜 10-6

8.9 〜 10-6
Bandgap, eV 10.8
Knoop Hardness, kg/mm2 415
Young's Modulus, GPa 138.5
Shear Modulus, GPa  54.66
Bulk Modulus, GPa 101.32
Apparent Elastic Limit, MPa 49.64
Poisson Ratio 0.276
Chemical properties
Solubility in water at 18°C 0.0076g (per 100g water)
Molecular Weight 62.31
 

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